Most certainly ;)
Oof. Is it one of the those?
If so: Oof²!
Typically those little funny DC connectors are called DC connectors for a reason :) All the metal ones I've come across so far have one of connections being the socket-casing - typically the outer one which (again) typically is ground and hence grounds the case. In your case: Congrats, you have AC on the case :frantics: So whatever you do, don't plug it in again until it's fixed :) 9VAC won't hurt, but it can easily kill all the electronics inside.
After careful consideration I'd like to change "isolate" to: "Throw it away and use a plastic one."
Unlikely. Yet: At some point attaching the front panel gives you sparks, which means that *something* on the CS is shorted to the panel - if it's ground, all good, if not you need to find the short. Multimeter > Beepmode > find out what's connected to the panel (with wires to the core unconnected)
Star wiring seems pretty popular. Run a connection from the core module (J2 or sth that has ground) to the base of the case and fix it to that with a nut, check with the multimeter if the connection is good. Usually you'd now run wires to all parts of the case from that spot. In your case a single wire to the front panel should do, since the rest seems to be connected (to be on the safe side, test with the multimeter and add wires if necessary).
Good thing you're working with small voltages then. Before you wire up a tube amp, make sure to ask again ;)